A practical and selective reduction of nitroarenes using elemental sulfur and mild base

被引：55

作者：

McLaughlin, Maureen A. ^{[1
]}

Barnes, David M. ^{[1
]}

机构：

[1] Abbott Labs, GPRD Proc Res & Dev, N Chicago, IL 60064 USA

来源：

TETRAHEDRON LETTERS | 2006年 / 47卷 / 51期

关键词：

AROMATIC NITRO-COMPOUNDS; CHEMOSELECTIVE REDUCTION; SODIUM-BOROHYDRIDE; AMINES; IRON; HYDRAZINE; ANILINES; MEDIA;

D O I：

10.1016/j.tetlet.2006.10.079

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A method was developed to reduce aromatic nitro compounds to the corresponding anilines using sulfur and base. The method tolerates a range of functional groups on the benzene ring, avoids the use of hydrogen and transition metals and provides the anilines in moderate to high yields. (c) 2006 Elsevier Ltd. All rights reserved.

引用

页码：9095 / 9097

页数：3

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