The formation of ReS2 inorganic fullerene-like structures containing Re4 parallelogram units and metal-metal bonds

被引:45
作者
Coleman, KS
Sloan, J
Hanson, NA
Brown, G
Clancy, GP
Terrones, M
Terrones, H
Green, MLH
机构
[1] Univ Oxford, Inorgan Chem Lab, Oxford OX1 3QR, England
[2] Univ Oxford, Dept Mat, Oxford OX1 3PH, England
[3] IPICyT, San Luis Potosi 78210, Mexico
关键词
D O I
10.1021/ja0261630
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The encapsulation of ReOx within ReS2 inorganic fullerene-like cages is described for the first time. The encapsulate was prepared by the sulfidization of both hand-milled and ball-milled samples of ReO2; partial conversion of the oxide to the sulfide was achieved with the degree of sulfidization depending on the exposure to the sulfidizing agent, H2S. Copyright © 2002 American Chemical Society.
引用
收藏
页码:11580 / 11581
页数:2
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