Cyclodextrins in polymer synthesis:: Free radical copolymerization of methylated β-cyclodextrin complexes of hydrophobic monomers with N-isopropylacrylamide in aqueous medium

被引:57
作者
Casper, P [1 ]
Glöckner, P [1 ]
Ritter, S [1 ]
机构
[1] Johannes Gutenberg Univ Mainz, Inst Organ Chem, D-55128 Mainz, Germany
关键词
D O I
10.1021/ma0001382
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Methylated beta-cyclodextrin (me-beta-CD) was used to form water-soluble host/guest complexes with the hydrophobic monomers n-butyl methacrylate (1), cyclohexyl methacrylate (2), isobornyl acrylate (3), isobornyl methaclylate (4), and styrene (5), respectively. The free-radical copolymerizations of the water-soluble N-isoplropylacrylamide (NIPAAm) with these complexed monomers were carried out in water at different molar ratios.
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页码:4361 / 4364
页数:4
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