Spontaneous resolution under supramolecular control

被引：485

作者：

Pérez-García, L

Amabilino, DB

机构：

[1] Univ Barcelona, Fac Farm, Lab Quim Organ, E-08028 Barcelona, Spain

[2] CSIC, Inst Ciencia Mat Barcelona, Bellaterra 08193, Spain

来源：

CHEMICAL SOCIETY REVIEWS | 2002年 / 31卷 / 06期

关键词：

D O I：

10.1039/b201099m

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The spontaneous resolution of enantiomers is an intriguing and important phenomenon in a number of research areas. Non-covalent interactions can play a key role in the process which can now be observed not only in crystals, but in liquid crystals, self-assembled monolayers, self-assembled fibres, and supramolecules self-assembled in solution. The evidence gathered in all of these areas is important for explaining the transfer of chirality from molecule to bulk, and in particular the spontaneous resolution of enantiomers.

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页码：342 / 356

页数：15

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