Catalytic C-C, C-N, and C-O Ullmann-Type Coupling Reactions

被引：1638

作者：

Monnier, Florian ^{[1
]}

Taillefer, Marc ^{[1
]}

机构：

[1] ENSCM, CNRS, Inst Charles Gerhardt Montpellier Architectures M, UMR 5253, F-34296 Montpellier 5, France

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2009年 / 48卷 / 38期

关键词：

arylation; catalysis; copper; cross-coupling; nucleophiles; NITROGEN-CONTAINING HETEROCYCLES; BETA-DICARBONYL COMPOUNDS; BOND-FORMING REACTIONS; ARYL HALIDES; HIGHLY EFFICIENT; LIGAND-FREE; PALLADIUM-FREE; AMINO-ACID; SOLVENT-FREE; SONOGASHIRA REACTION;

D O I：

10.1002/anie.200804497

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Copper-catalyzed Ullmann condensations are key reactions for the formation of carbon-heteroatom and carbon-carbon bonds in organic synthesis. These reactions can lead to structural moieties that are prevalent in building blocks of active molecules in the life sciences and in many material precursors. An increasing number of publications have appeared concerning Ullmann-type intermolecular reactions for the coupling of aryl and vinyl halides with N, O, and C. nucleophiles, and this Minireview highlights recent and major developments in this topic since 2004. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：6954 / 6971

页数：18

共 265 条

[1] Synthetic approaches to sterically hindered N-arylimidazoles through copper-catalyzed coupling reactions
Alcalde, E
Dinarès, I
Rodríguez, S
de Miguel, CG
[J]. EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2005, 2005 (08) : 1637 - 1643
[2] Non-conventional methodologies for transition-metal catalysed carbon-carbon coupling: a critical overview. Part 2: The Suzuki reaction
Alonso, Francisco
Beletskaya, Irina P.
Yus, Miguel
[J]. TETRAHEDRON, 2008, 64 (14) : 3047 - 3101
[3] Orthogonal Pd- and Cu-based catalyst systems for C- and N-arylation of oxindoles
Altman, Ryan A.
Hyde, Alan M.
Huang, Xiaohua
Buchwald, Stephen L.
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (29) : 9613 - 9620
[4] Pyrrole-2-carboxylic acid as a ligand for the Cu-catalyzed reactions of primary anilines with aryl halides
Altman, Ryan A.
Anderson, Kevin W.
Buchwald, Stephen L.
[J]. JOURNAL OF ORGANIC CHEMISTRY, 2008, 73 (13) : 5167 - 5169
[5] An improved cu-based catalyst system for the reactions of alcohols with aryl halides
Altman, Ryan A.
Shafir, Alexandr
Choi, Alice
Lichtor, Phillip A.
Buchwald, Stephen L.
[J]. JOURNAL OF ORGANIC CHEMISTRY, 2008, 73 (01) : 284 - 286
[6] Copper-catalyzed N-arylation of imidazoles and benzimidazoles
Altman, Ryan A.
Koval, Erica D.
Buchwald, Stephen L.
[J]. JOURNAL OF ORGANIC CHEMISTRY, 2007, 72 (16) : 6190 - 6199
[7] Cu-catalyzed N- and O-arylation of 2-, 3-, and 4-hydroxypyridines and hydroxyquinolines
Altman, Ryan A.
Buchwald, Stephen L.
[J]. ORGANIC LETTERS, 2007, 9 (04) : 643 - 646
[8] 4,7-Dimethoxy-1,10-phenanthroline:: An excellent ligand for the Cu-catalyzed N-arylation of imidazoles
Altman, Ryan A.
Buchwald, Stephen L.
[J]. ORGANIC LETTERS, 2006, 8 (13) : 2779 - 2782
[9] Copper(I)-catalyzed synthesis of ferrocenyl aryl ethers
an der Heiden, MR
Frey, GD
Plenio, H
[J]. ORGANOMETALLICS, 2004, 23 (14) : 3548 - 3551
[10] [Anonymous], 2008, ANGEW CHEM INT EDIT

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