Flow injection analysis for the determination of thiabendazole and fuberidazole in water by spectrofluorimetry

被引:19
作者
Garcia, LF [1 ]
Aaron, JJ [1 ]
机构
[1] UNIV PARIS 7 DENIS DIDEROT,ASSOC CNRS URA 34,INST TOPOL & DYNAM SYST,F-75005 PARIS,FRANCE
关键词
flow injection; spectrofluorimetry; thiabendazole determination; fuberidazole determination; water analysis;
D O I
10.1007/BF01242335
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
Flow-injection analysis (FIA) is proposed for determining thiabendazole (TBZ) and fuberidazole (FBZ) by spectrofluorimetry. A pH 2 aqueous solution was found to be the optimal solvent for the rapid, precise and sensitive fluorescence analysis of both fungicides. Linear dynamic graphs were established over a concentration range of two orders of magnitude. Limits of detection were 0.7 ng/ml for TBZ and 0.1 ng/ml for FBZ. Relative standard deviations were 0.5 and 0.8% for TBZ and FBZ, respectively. The method was applied to the determination of both compounds in spiked river and tap water samples, with satisfactory recoveries.
引用
收藏
页码:289 / 294
页数:6
相关论文
共 33 条
[1]   FLOW-INJECTION TECHNIQUES FOR WATER MONITORING [J].
ANDREW, KN ;
BLUNDELL, NJ ;
PRICE, D ;
WORSFOLD, PJ .
ANALYTICAL CHEMISTRY, 1994, 66 (18) :A916-A922
[2]  
ARENAS RV, 1994, J AOAC INT, V77, P710
[3]  
ARENAS RV, 1995, J AOAC INT, V78, P642
[4]  
BENSON R L, 1989, Analytical Proceedings, V26, P385
[5]  
Brennecke R., 1984, Pflanzenschutz-Nachrichten Bayer, V37, P46
[6]  
BUSHWAY RJ, 1995, J AOAC INT, V78, P815
[7]  
Coly A, 1996, ANALUSIS, V24, P107
[8]   PHOTOCHEMICAL-SPECTROFLUOROMETRIC METHOD FOR THE DETERMINATION OF SEVERAL AROMATIC INSECTICIDES [J].
COLY, A ;
AARON, JJ .
ANALYST, 1994, 119 (06) :1205-1209
[9]  
CRANK G, 1982, AUST J CHEM, V33, P775
[10]   CONTINUOUS MONITORING BY UNSEGMENTED FLOW TECHNIQUES - STATE OF THE ART AND PERSPECTIVES [J].
DECASTRO, MDL .
TALANTA, 1989, 36 (05) :591-599