M(3,2)-edge x-ray absorption near-edge structure spectroscopy: An alternative probe to the L(3,2)-edge near-edge structure for the unoccupied densities of d states of 5d metals

被引:54
作者
Sham, TK
Naftel, SJ
Coulthard, I
机构
[1] Department of Chemistry, University of Western Ontario, London
关键词
D O I
10.1063/1.361483
中图分类号
O59 [应用物理学];
学科分类号
摘要
We report M(3,2)-edge x-ray absorption near-edge structure (XANES) measurements for a series of 5d metals, Ta, W, Pt, and Au using a total electron yield technique. It is found that the M(3,2) XANES absorption features and their systematics are comparable to their L(3,2) counterparts. These results clearly indicate that M(3,2)-edge XANES can be used as an alternative probe for the unoccupied densities of d states of the 5d metals and their compounds. The implication of these results is discussed. (C) 1996 American Institute of Physics.
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页码:7134 / 7138
页数:5
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