High figure of merit in Eu-filled CoSb3-based skutterudites

被引:207
作者
Lamberton, GA [1 ]
Bhattacharya, S
Littleton, RT
Kaeser, MA
Tedstrom, RH
Tritt, TM
Yang, J
Nolas, GS
机构
[1] Clemson Univ, Dept Phys & Astron, Clemson, SC 29634 USA
[2] GM Corp, R&D & Planning, Warren, MI 48090 USA
[3] Univ S Florida, Dept Phys, Tampa, FL 33620 USA
关键词
D O I
10.1063/1.1433911
中图分类号
O59 [应用物理学];
学科分类号
摘要
We report measurements of electrical resistivity, thermopower, thermal conductivity, and Hall coefficient of polycrystalline Eu-doped CoSb3-based skutterudites with compositions Eu0.20Co4Sb12, Eu0.43Co4Sb11.59Ge0.31, and Eu0.42Co4Sb11.37Ge0.50. The relatively high mobility of these compounds, as compared to that of La- and Ce-filled skutterudites, may play a role in the large thermoelectric figure of merit (ZT>1 at 700 K) of Eu0.42Co4Sb11.37Ge0.50. We discuss the significant potential of these compounds for thermoelectric applications. (C) 2002 American Institute of Physics.
引用
收藏
页码:598 / 600
页数:3
相关论文
共 11 条
[1]   Transition-metal pentatellurides as potential low-temperature thermoelectric refrigeration materials [J].
Littleton, RT ;
Tritt, TM ;
Kolis, JW ;
Ketchum, DR .
PHYSICAL REVIEW B, 1999, 60 (19) :13453-13457
[2]  
Littleton RT, 1999, MATER RES SOC SYMP P, V545, P137
[3]  
Nolas G. S., 2001, THERMOELECTRICS BASI
[4]   High figure of merit in partially filled ytterbium skutterudite materials [J].
Nolas, GS ;
Kaeser, M ;
Littleton, RT ;
Tritt, TM .
APPLIED PHYSICS LETTERS, 2000, 77 (12) :1855-1857
[5]   Effect of partial void filling on the lattice thermal conductivity of skudderudites [J].
Nolas, GS ;
Cohn, JL ;
Slack, GA .
PHYSICAL REVIEW B, 1998, 58 (01) :164-170
[6]   The effect of rare-earth filling on the lattice thermal conductivity of skutterudites [J].
Nolas, GS ;
Slack, GA ;
Morelli, DT ;
Tritt, TM ;
Ehrlich, AC .
JOURNAL OF APPLIED PHYSICS, 1996, 79 (08) :4002-4008
[7]   Skutterudites: A phonon-glass-electron crystal approach to advanced thermoelectric energy conversion applications [J].
Nolas, GS ;
Morelli, DT ;
Tritt, TM .
ANNUAL REVIEW OF MATERIALS SCIENCE, 1999, 29 :89-116
[8]   Apparatus for the rapid measurement of electrical transport properties for both "needle-like" and bulk materials [J].
Pope, AL ;
Littleton, RT ;
Tritt, TM .
REVIEW OF SCIENTIFIC INSTRUMENTS, 2001, 72 (07) :3129-3131
[9]  
Tritt TM, 2001, SEMICONDUCT SEMIMET, V69, P25
[10]  
Uher C, 2001, SEMICONDUCT SEMIMET, V69, P139