The interpretation of XPS spectra: Insights into materials properties

被引：378

作者：

Bagus, Paul S. ^{[1
]}

Ilton, Eugene S. ^{[2
]}

Nelin, Connie J. ^{[3
]}

机构：

[1] Univ N Texas, Dept Chem, Denton, TX 76203 USA

[2] Pacific NW Natl Lab, Richland, WA 99352 USA

[3] CJ Nelin Consulting, Austin, TX USA

来源：

SURFACE SCIENCE REPORTS | 2013年 / 68卷 / 02期

关键词：

X-RAY PHOTOEMISSION; BINDING-ENERGY SHIFTS; ELECTRONIC POPULATION ANALYSIS; HARTREE-FOCK CALCULATIONS; MOLECULAR WAVE FUNCTIONS; DENSITY-FUNCTIONAL THEORY; EFFECTIVE CORE POTENTIALS; ORBITAL CLUSTER-MODEL; 1S HOLE STATES; MULTIPLET STRUCTURE;

D O I：

10.1016/j.surfrep.2013.03.001

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070305 [高分子化学与物理];

摘要：

We review basic and advanced concepts needed for the correct analysis of XPS features. We place these concepts on rigorous foundations and explore their physical and chemical meanings without stressing the derivation of the mathematical formulations, which can be found in the cited literature. The significance and value of combining theory and experiment is demonstrated by discussions of the physical and chemical origins of the main and satellite XPS features for a variety of molecular and condensed phase materials. (c) 2013 Elsevier B.V. All rights reserved.

引用

页码：273 / 304

页数：32

共 177 条

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