A model for electrochemical electron transfer with strong electronic coupling

被引：20

作者：

Mohr, J.

Schmickler, W. ^{[1
]}

Badiali, J. P.

机构：

[1] Univ Ulm, Dept Theoret Chem, D-89069 Ulm, Germany

[2] Univ Paris 06, Lab Struct & Reactiv Interfaces, F-75230 Paris 05, France

来源：

CHEMICAL PHYSICS | 2006年 / 324卷 / 01期

关键词：

D O I：

10.1016/j.chemphys.2005.12.001

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Electron exchange between a metal or semiconducting electrode and a solvated reactant is calculated by Green-function techniques. In the wide band approximation the time development of a system prepared in a definite electronic state can be calculated exactly. The results are valid for all coupling strengths, and are applied both to photoexcited and to thermally-induced transfer. (c) 2005 Elsevier B.V. All rights reserved.

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页码：140 / 147

页数：8

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