Theory of molecular deformations and mesomorphic behavior of dendrimers

被引:9
作者
Terzis, AF [1 ]
Vanakaras, AG [1 ]
Photinos, DJ [1 ]
机构
[1] Univ Patras, Dept Phys, Patras 26500, Greece
来源
MOLECULAR CRYSTALS AND LIQUID CRYSTALS SCIENCE AND TECHNOLOGY SECTION A-MOLECULAR CRYSTALS AND LIQUID CRYSTALS | 1999年 / 330卷
关键词
molecular deformations; liquid crystal dendrimers; phase transitions; molecular theory;
D O I
10.1080/10587259908025629
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
We present a simple statistical theory of anisotropic fluid phases consisting of deformable molecules and we use it to describe the self-organization of liquid crystalline dendrimers in the limit of very densely attached mesogenic units. We perform calculations for model-systems of spherical molecules that can deform into rod-like or disc-like states and we determine their mesomorphic range as a function of molecular shape parameters and intrinsic conformational probability.
引用
收藏
页码:1761 / 1768
页数:8
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