Stereoselectivity in the formation of crystalline inclusion complexes of poly(3-hydroxybutyrate)s with cyclodextrins

被引：64

作者：

Shuai, XT ^{[1
]}

Probeni, FE ^{[1
]}

Wei, M ^{[1
]}

Bullions, T ^{[1
]}

Tonelli, AE ^{[1
]}

机构：

[1] N Carolina State Univ, Coll Text, Fiber & Polymer Sci Program, Raleigh, NC 27695 USA

来源：

MACROMOLECULES | 2002年 / 35卷 / 09期

关键词：

D O I：

10.1021/ma012038h

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The stereoselectivity in the formation of crystalline inclusion complexes (IC) of poly(3-hydroxybutyrates)s (PHB) with cyclodextrins (CD) was discussed. It was observed that a-PHB was not able to form ICs with α- or β- CDs. The analysis suggested that the α- or β-CD cavity was too small to accomodate the a-PHB chain in low-energy extended conformations necessary for inclusion.

引用

页码：3778 / 3780

页数：3

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