Crystal structure, dissolution, and deposition of a 5 nm functionalized metal-organic great rhombicuboctahedron

被引：158

作者：

Furukawa, Hiroyasu ^{[1
]}

Kim, Jaheon

Plass, Katherine E.

Yaghi, Omar M.

机构：

[1] Univ Calif Los Angeles, Dept Chem & Biochem, Los Angeles, CA 90095 USA

[2] Univ Calif Los Angeles, Ctr Reticular Mat Res, Calif Nanosyst Inst, Los Angeles, CA 90095 USA

[3] Soongsil Univ, Dept Chem, Seoul 156743, South Korea

[4] Soongsil Univ, CAMDRC, Seoul 156743, South Korea

[5] Univ Michigan, Dept Chem, Ann Arbor, MI 48109 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2006年 / 128卷 / 26期

关键词：

D O I：

10.1021/ja062491e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A metal-organic great rhombicuboctahedron (termed MOP-18) was functionalized with extended alkyl chains and crystallized. It has 12 rigid square-shaped Cu2(CO2)4 paddle-wheel building units and 24 5-dodecoxybenzene-1,3-dicarboxylate links. MOP-18 is soluble in a variety of organic solvents, such as tetrahydrofuran, chloroform, and toluene, which enabled its assembly on graphite substrate and its observation by scanning tunneling microscopy. Copyright © 2006 American Chemical Society.

引用

页码：8398 / 8399

页数：2

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