Electrostatic-field-induced enhancement of gas mixture separation in metal-organic frameworks: A computational study

被引：136

作者：

Yang, Qingyuan

Zhong, Chongli ^{[1
]}

机构：

[1] Beijing Univ Chem Technol, Dept Chem Engn, Beijing 100029, Peoples R China

[2] Beijing Univ Chem Technol, Minist Educ, Key Lab Nanomat, Beijing 100029, Peoples R China

来源：

CHEMPHYSCHEM | 2006年 / 7卷 / 07期

关键词：

adsorption; gas mixtures; metal-organic frameworks; microporous materials; molecular modeling;

D O I：

10.1002/cphc.200600191

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

(Graph Presented) Ordered microdomains with different electrostatic field strengths exist in certain metal-organic frameworks (MOFs; see picture), and the electrostatic interactions in MOFs can enhance the separation of some gas mixtures, demonstrating that MOFs have great potential for adsorption separations. © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.

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页码：1417 / 1421

页数：5

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