Collisional depolarisation in electronically excited radicals

被引:15
作者
Chadwick, H. [1 ]
Brouard, M. [1 ]
Perkins, T. [1 ]
Aoiz, F. J. [2 ]
机构
[1] Univ Oxford, Dept Chem, Phys & Theoret Chem Lab, Oxford OX1 3QZ, England
[2] Univ Complutense, Dept Quim Fis, Fac Quim, E-28040 Madrid, Spain
基金
英国工程与自然科学研究理事会;
关键词
potential energy surface; depolarisation; angular momentum; inelastic collisions; alignment; orientation; ROTATIONAL ENERGY-TRANSFER; DIFFERENTIAL CROSS-SECTIONS; QUANTUM-BEAT SPECTROSCOPY; JZ-PRESERVING PROPENSITIES; SHELL DIATOMIC-MOLECULES; INELASTIC-SCATTERING; POLARIZATION SPECTROSCOPY; ANGULAR-MOMENTUM; VECTOR CORRELATIONS; DOUBLE-RESONANCE;
D O I
10.1080/0144235X.2014.891855
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Recent work on collisional depolarisation in electronically excited radicals is reviewed, with a focus on the NO(A) and OH(A) radicals in collisions with rare gas atoms. The mechanism of depolarisation, and its competition with other collisional processes, is investigated using a combination of experimental and theoretical methods. The present state of the field is also put into context with other, related work in similar areas.
引用
收藏
页码:79 / 123
页数:45
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