Asymmetric hydroformylation of allylic alcohols catalyzed by Rh(I)-(R,S)-BINAPHOS

被引:54
作者
Nozaki, K
Li, WG
Horiuchi, T
Takaya, H
机构
[1] Department of Material Chemistry, Graduate School of Engineering, Kyoto University, Kyoto 606-01, Yoshida, Sakyo-ku
关键词
D O I
10.1016/S0040-4039(97)00988-X
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Chiral lactones 4a-e were synthesized by the asymmetric hydroformylation of allylic alcohols 1a-e and 5 catalyzed by a rhodium(1) complex of a chiral phosphine-phosphite, (R,S)-BINAPHOS, followed by the silver(I) oxidation. (C) 1997 Elsevier Science Ltd.
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页码:4611 / 4614
页数:4
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