Enantioselective guest binding and dynamic resolution of cationic ruthenium complexes by a chiral metal-ligand assembly

被引：151

作者：

Fiedler, D ^{[1
]}

Leung, DH

Bergman, RG

Raymond, KN

机构：

[1] Univ Calif Berkeley, Lawrence Berkeley Lab, Div Chem Sci, Berkeley, CA 94720 USA

[2] Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2004年 / 126卷 / 12期

关键词：

D O I：

10.1021/ja039225a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A supramolecular metal?ligand assembly encapsulates a variety of cationic half-sandwich ruthenium complexes. Due to the chirality of both host and guest, chiral recognition is observed with diastereomeric excesses up to 70%. The chiral cavity can be used to carry out a dynamic resolution of the rapidly equilibrating enantiomers of the chiral organometallic guest. Copyright © 2004 American Chemical Society.

引用

页码：3674 / 3675

页数：2

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