The first route toward oxygenated monocarbocyclic terpenoids:: synthesis of elegansidiol, a new sesquiterpene from Santolina elegans

被引：23

作者：

Barrero, AF ^{[1
]}

Alvarez-Manzaneda, EJ

Herrador, MM

Alvarez-Manzaneda, R

Quilez, J

Chahboun, R

Linares, P

Rivas, A

机构：

[1] Univ Granada, Dept Quim Organ, Inst Biotechnol, E-18071 Granada, Spain

[2] Univ Almeria, Fac Ciencias, Dept Quim Organ, Almeria 04120, Spain

来源：

TETRAHEDRON LETTERS | 1999年 / 40卷 / 47期

关键词：

terpenoids; cyclization;

D O I：

10.1016/S0040-4039(99)01730-X

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

This paper describes the isolation of elegansidiol (1), a new monocyclic sesquiterpenic alcohol, together with the known monocyclic triterpene achilleol A (2), both from Santolina elegans. The structure of 1 was confirmed by synthesis starting from 6,7-epoxygeranyl acetate (6), constituting the first route towards this type of compound. (C) 1999 Elsevier Science Ltd. All rights reserved.

引用

页码：8273 / 8276

页数：4

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