Methylcyclopentadienyl-vanadium(III) complexes

被引：8

作者：

Böttcher, C ^{[1
]}

Schmidt, H ^{[1
]}

Rehder, D ^{[1
]}

机构：

[1] Univ Hamburg, Inst Anorgan & Angew Chem, D-20146 Hamburg, Germany

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1999年 / 580卷 / 01期

关键词：

isocyanide; methylcyclopentadienyl; vanadium;

D O I：

10.1016/S0022-328X(98)01080-8

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

[(MeCp)VCl2(PEt3)(2)] (1) and [(MeCp)(2)VCl] (4) (MeCp = eta(5)-C5H4CH3)have been obtained from the reaction between VCl3 and NaMeCp in THF in the presence (1) and absence (4), respectively, of PEt3. The reaction of VCl3 and NaMeCp in the presence of CNt-Bu yielded (impure) [(MeCp)VCl2(CNt-Bu)(2)] (3) and, as a by-product, [(MeCp)(2)V(CNt-Bu)(2)][VCl4(THF)(2)] (2). The crystal and molecular structures of 1, 2 and 4 have been determined. (C) 1999 Elsevier Science S.A. All rights reserved.

引用

页码：72 / 76

页数：5

共 21 条

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