Mass-resolved multiphoton ionization spectroscopy of jet-cooled Cl-2- .2. The (2+1) REMPI spectrum between 76000 and 90000 cm(-1)

被引：11

作者：

AlKahali, MSN

Donovan, RJ

Lawley, KP

Ridley, T

机构：

[1] Department of Chemistry, University of Edinburgh, Edinburgh EH9 3JJ, West Mains Road

来源：

JOURNAL OF CHEMICAL PHYSICS | 1996年 / 104卷 / 05期

关键词：

D O I：

10.1063/1.470980

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The (2 + 1) resonance-enhanced multiphoton ionization (REMPI) spectrum of Cl-2 has been recorded between 76 000 and 90 000 cm(-1). The origins of twenty Rydberg states are located, with the s series (4s - 8s) generally exhibiting four Omega components and the d series (3d-5d) two components for each value of n. Vibronic coupling between the beta(1(g)) ion-pair state and the 3d and 4d (Omega = 1) states is pronounced, necessitating the use of mass resolved REMPI for the analysis of these vibronically mixed states. (C) 1996 American Institute of Physics.

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页码：1833 / 1838

页数：6

相关论文

共 12 条

[1] Mass-resolved multiphoton ionization spectroscopy of jet-cooled Cl-2- .1. Bound-free-bound spectroscopy [J].

AlKahali, MSN ;

Donovan, RJ ;

Lawley, KP ;

Min, ZY ;

Ridley, T .

JOURNAL OF CHEMICAL PHYSICS, 1996, 104 (05) :1825-1832

[2] ABSORPTION-SPECTRUM OF ATOMIC CHLORINE - 3P5 P-2(3/2)O,1/2-3P4NS,ND [J].

CANTU, AM ;

PARKINSON, WH ;

GRISENDI, T ;

TAGLIAFERRI, G .

PHYSICA SCRIPTA, 1985, 31 (06) :579-586

[3] THE RESONANCE ENHANCED (2+1) MULTIPHOTON IONIZATION SPECTRUM OF I-2 [J].

DONOVAN, RJ ;

FLOOD, RV ;

LAWLEY, KP ;

YENCHA, AJ ;

RIDLEY, T .

CHEMICAL PHYSICS, 1992, 164 (03) :439-450

[4] RESONANCE-ENHANCED MULTIPHOTON IONIZATION SPECTRA OF THE E0(+)(P-3(2)) AND F0(+)(P-3(0)) ION-PAIR STATES OF ICL [J].

DONOVAN, RJ ;

GOODE, JG ;

LAWLEY, KP ;

RIDLEY, T ;

YENCHA, AJ .

JOURNAL OF PHYSICAL CHEMISTRY, 1994, 98 (09) :2236-2241

[5]

JURETA J, 1982, Z PHYS A, V304, P134

[6] PHOTOELECTRON SPECTROSCOPIC STUDIES OF MULTIPHOTON PROCESSES IN MOLECULAR CHLORINE INVOLVING THE 2 1-PI-G RYDBERG STATE [J].

KOENDERS, BG ;

KOECKHOVEN, SM ;

KUIK, GJ ;

DRABE, KE ;

DELANGE, CA .

JOURNAL OF CHEMICAL PHYSICS, 1989, 91 (10) :6042-6051

[7] VIBRONIC COUPLING BETWEEN RYDBERG AND ION-PAIR STATES OF I-2, INVESTIGATED BY (2+1)-RESONANCE-ENHANCED MULTIPHOTON IONIZATION SPECTROSCOPY [J].

LAWLEY, KP ;

RIDLEY, T ;

MIN, Z ;

WILSON, PJ ;

ALKAHALI, MSN ;

DONOVAN, RJ .

CHEMICAL PHYSICS, 1995, 197 (01) :37-50

[8] SPECTROSCOPY AND PHOTOPHYSICS OF 1-PI-G AND 3-PI-G RYDBERG, ION-PAIR STATES OF CL2, REVEALED BY MULTIPHOTON IONIZATION [J].

LI, LP ;

LIPERT, RJ ;

PARK, H ;

CHUPKA, WA ;

COLSON, SD .

JOURNAL OF CHEMICAL PHYSICS, 1988, 88 (08) :4608-4613

[9] RESONANCE ENHANCED (2 + 1) MULTIPHOTON IONIZATION SPECTRUM OF BR-2 - THE LOWER RYDBERG STATES [J].

RIDLEY, T ;

LAWLEY, KP ;

DONOVAN, RJ ;

YENCHA, AJ .

CHEMICAL PHYSICS, 1990, 148 (2-3) :315-323

[10] ELECTRONIC-STRUCTURE OF CL2 FROM 5 TO 15 EV BY ELECTRON-ENERGY LOSS SPECTROSCOPY [J].

SPENCE, D ;

HUEBNER, RH ;

TANAKA, H ;

DILLON, MA ;

WANG, RG .

JOURNAL OF CHEMICAL PHYSICS, 1984, 80 (07) :2989-2996