Renewable phenols production by catalytic microwave pyrolysis of Douglas fir sawdust pellets with activated carbon catalysts

被引：112

作者：

Bu, Quan ^{[1
]}

Lei, Hanwu ^{[1
]}

Wang, Lu ^{[1
]}

Wei, Yi ^{[1
]}

Zhu, Lei ^{[1
]}

Liu, Yupeng ^{[1
]}

Liang, Jing ^{[1
]}

Tang, Juming ^{[1
]}

机构：

[1] Washington State Univ, Bioprod Sci & Engn Lab, Dept Biol Syst Engn, Richland, WA 99354 USA

来源：

BIORESOURCE TECHNOLOGY | 2013年 / 142卷

关键词：

Activated carbon; Catalytic pyrolysis; Recycling; Phenols; Reaction mechanism; BIO-OIL; ASSISTED PYROLYSIS; PARTICLE-SIZE; BIOMASS; HYDROGEN; FUELS; CELLULOSE; RESINS;

D O I：

10.1016/j.biortech.2013.05.073

中图分类号：

S2 [农业工程];

学科分类号：

082806 [农业信息与电气工程];

摘要：

The effects of different activated carbon (AC) catalysts based on various carbon sources on products yield and chemical compositions of upgraded pyrolysis oils were investigated using microwave pyrolysis of Douglas fir sawdust pellets. Results showed that high amounts of phenols were obtained (74.61% and 74.77% in the upgraded bio-oils by DARCO MRX (wood based) and DARCO 830 (lignite coal based) activated carbons, respectively). The catalysts recycling test of the selected catalysts indicated that the carbon catalysts can be reused for at least 3-4 times and produced high concentrations of phenol and phenolic compounds. The chemical reaction mechanism for phenolics production during microwave pyrolysis of biomass was analyzed. (C) 2013 Elsevier Ltd. All rights reserved.

引用

页码：546 / 552

页数：7

共 37 条

[1]

Production of monomeric phenols by thermochemical conversion of biomass: a review [J].

Amen-Chen, C ;

Pakdel, H ;

Roy, C .

BIORESOURCE TECHNOLOGY, 2001, 79 (03) :277-299

[2]

Production of phenols and biofuels by catalytic microwave pyrolysis of lignocellulosic biomass [J].

Bu, Quan ;

Lei, Hanwu ;

Ren, Shoujie ;

Wang, Lu ;

Zhang, Qin ;

Tang, Juming ;

Ruan, Roger .

BIORESOURCE TECHNOLOGY, 2012, 108 :274-279

[3]

Phenol and phenolics from lignocellulosic biomass by catalytic microwave pyrolysis [J].

Bu, Quan ;

Lei, Hanwu ;

Ren, Shoujie ;

Wang, Lu ;

Holladay, John ;

Zhang, Qin ;

Tang, Juming ;

Ruan, Roger .

BIORESOURCE TECHNOLOGY, 2011, 102 (13) :7004-7007

[4]

Overview of applications of biomass fast pyrolysis oil [J].

Czernik, S ;

Bridgwater, AV .

ENERGY & FUELS, 2004, 18 (02) :590-598

[5]

Comparative study of conventional and microwave-assisted pyrolysis, steam and dry reforming of glycerol for syngas production, using a carbonaceous catalyst [J].

Fernandez, Y. ;

Arenillas, A. ;

Bermudez, J. M. ;

Menendez, J. A. .

JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS, 2010, 88 (02) :155-159

[6]

Pyrolysis of glycerol over activated carbons for syngas production [J].

Fernandez, Y. ;

Arenillas, A. ;

Diez, M. A. ;

Pis, J. J. ;

Menendez, J. A. .

JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS, 2009, 84 (02) :145-150

[7]

Holladay J. E., 2007, PNNL16983

[8]

A study on experimental characteristic of microwave-assisted pyrolysis of microalgae [J].

Hu, Zhifeng ;

Ma, Xiaoqian ;

Chen, Chunxiang .

BIORESOURCE TECHNOLOGY, 2012, 107 :487-493

[9]

Synthesis of transportation fuels from biomass: Chemistry, catalysts, and engineering [J].

Huber, George W. ;

Iborra, Sara ;

Corma, Avelino .

CHEMICAL REVIEWS, 2006, 106 (09) :4044-4098

[10]

A review on bio-oil production from biomass by using pyrolysis method [J].

Isahak, Wan Nor Roslam Wan ;

Hisham, Mohamed W. M. ;

Yarmo, Mohd Ambar ;

Hin, Taufiq-yap Yun .

RENEWABLE & SUSTAINABLE ENERGY REVIEWS, 2012, 16 (08) :5910-5923

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