New synthesis routes to lithium and cesium cyanide salts

被引：26

作者：

Markley, TJ ^{[1
]}

Toby, BH ^{[1
]}

Pearlstein, RM ^{[1
]}

Ramprasad, D ^{[1
]}

机构：

[1] NIST,DIV REACTOR RADIAT,GAITHERSBURG,MD 20899

来源：

INORGANIC CHEMISTRY | 1997年 / 36卷 / 15期

关键词：

D O I：

10.1021/ic961395j

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

New simple synthesis routes for two alkali cyanide salts, LiCN, and CsCN have been demonstrated. A crystal structure of LiCN . 0.6DMF . 0.4DMAc was obtained. The structure can be described as infinite sheets of Li pairs, linked end-on by cyanide ligands. The Li atoms are bridged above and below the sheet by a DMF or DMAc oxygen atom.

引用

页码：3376 / &

页数：4

共 8 条

[1] HIGH-PURITY CYANIDES - A DYING TECHNOLOGY REVIVED [J].