Synthesis of trans-[Mo(O)(F)(dppe)(2)](BF4), trans-[Mo(O)(OH)(dppe)(2)](ClO4), and trans-[Mo(O)(2)(dppe)(2)].2L (L=H2O, CH3OH, CH3CH2OH, CH3CHOHCH3). Crystal structure of trans-[Mo(O)(2)(dppe)(2)].2CH(3)OH

被引：8

作者：

Bendix, J ^{[1
]}

Birkedal, H ^{[1
]}

Bogevig, A ^{[1
]}

机构：

[1] UNIV COPENHAGEN, CTR CRYSTALLOG STUDIES, DK-2100 COPENHAGEN, DENMARK

来源：

INORGANIC CHEMISTRY | 1997年 / 36卷 / 13期

关键词：

D O I：

10.1021/ic9614071

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The solvates trans-[Mo(O)(2)(dppe)(2)].2L. (L = H2O, CH3OH, CH3CH2OH, CH3CHOHCH3) have been prepared by letting trans-[Mo(O)(F)(dppe)(2)](BF4) react with NEt4OH in mixtures of acetone and the respective hydrogen-bond done; solvents. This series of compounds is the first example of adduct formation between a trans-dioxo d(2) metal complex and potential substrates for oxidation. These compounds can be protonated in two steps. The electronic spectra of the trans-oxo-hydroxo and trans-ore-aqua species are consistent with the lowest energy transition being of d(xy) --> {d(zx), d(yz)} character.

引用

页码：2702 / +

页数：3

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