Synthesis of (eta(5)-pentamethylcyclopentadienyl)ruthenium pi-complexes of heterocycles by nucleophilic substitution

被引：21

作者：

Dembek, AA

Fagan, PJ

机构：

[1] Experimental Station, DuPont Ctrl. R. and D., Wilmington

来源：

ORGANOMETALLICS | 1996年 / 15卷 / 04期

关键词：

D O I：

10.1021/om9507686

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Cp*Ru+ pi-complexes of 1,2-dihalo- and 1,2,4,5- tetrahaloaromatics are readily prepared by reaction of the arenes with Cp*Ru(CH3CN)(3)(+)OTf(-). The pi-complexes undergo nucleophilic substitutions with 1 or 2 equiv of 1,2-disubstituted aromatic nucleophiles, leading to symmetrically and unsymmetrically substituted organometallic heterocycles.

引用

页码：1319 / 1322

页数：4

共 24 条

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