Layered double hydroxides;
Humic substances;
Adsorption;
Water treatment;
D O I:
10.1016/j.colsurfa.2008.08.002
中图分类号:
O64 [物理化学(理论化学)、化学物理学];
学科分类号:
070304 ;
081704 ;
摘要:
Layered double hydroxides (LDHs) with Mg2+ and Fe3+ cations and having chloride or carbonate ions in the interlayer region have been prepared and characterized by different methods. The diameter of the prepared particle was in the range of 0.4-0.6 mu m. The adsorption of humic acid onto chloride and carbonate intercalated LDHs with Mg/Fe (ratio = 4:1)was studied by adsorption isotherms at different ionic strengths. The adsorption of humic acid onto LDHs occurred by ion exchange with both the intercalated and surface anions of the LDH and ligand exchange reactions with surface groups. The contribution of both mechanisms to the total HA adsorption was estimated. (C) 2008 Elsevier B.V. All rights reserved.