A new cyclometalated rhenium(I)(CO)+4 complex

被引：12

作者：

Czerwieniec, R

Kapturkiewicz, A

Nowacki, J

机构：

[1] Polish Acad Sci, Inst Phys Chem, PL-01224 Warsaw, Poland

[2] Warsaw Univ, Dept Chem, PL-02093 Warsaw, Poland

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2005年 / 8卷 / 12期

关键词：

rhenium; 2-phenylbenzothiazole; transition metal complexes; X-ray crystallography; UV-Vis spectroscopy;

D O I：

10.1016/j.inoche.2005.09.005

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reaction of Re(CO)(5)Cl with 2-phenylbenzothiazole (H Phi BT) afforded the cyclometalated Re(CO)(4)(Phi BT) complex with the molecular structure of the obtained product confirmed by X-ray investigations. Re(CO)(4)(Phi BT) shows intense, hardly dependent on environment, luminescence originating from the pi-pi* Phi BT intraligand electronic transition. The investigated Re(CO)(4)(Phi BT) complex can be considered as a potentially applicable "triplet emitter" for OLED devices. (c) 2005 Elsevier B.V. All rights reserved.

引用

收藏

页码：1101 / 1104

页数：4

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