X-ray, thermal and infrared spectroscopic studies on lithium and sodium oxalate hydrates

被引：14

作者：

Dahale, ND ^{[1
]}

Chawla, KL ^{[1
]}

Jayadevan, NC ^{[1
]}

Venugopal, V ^{[1
]}

机构：

[1] BHABHA ATOM RES CTR,DIV FUEL CHEM,BOMBAY 400085,MAHARASHTRA,INDIA

来源：

THERMOCHIMICA ACTA | 1997年 / 293卷 / 1-2期

关键词：

decomposition; DTA; lithium/sodium uranyl oxalate; x-ray diffraction;

D O I：

10.1016/S0040-6031(97)00015-4

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

Lithium uranyl oxalate hydrate, Li2UO2(C2O4)(2) . 5H(2)O and sodium uranyl oxalate hydrate, Na2UO2(C2O4). 4H(2)O have been prepared and characterized by chemical and thermal analyses as well as X-ray diffraction and infrared spectroscopy. X-ray powder data show that the compounds belong to a monoclinic system. Thermal decomposition and infrared studies show that the compounds decompose to monouranates through the formation of alkali metal carbonates and UO2 as intermediates. (C) 1997 Elsevier Science B.V.

引用

页码：163 / 166

页数：4