Control of vertex geometry, structure dimensionality, functionality, and pore metrics in the reticular synthesis of crystalline metal-organic frameworks and polyhedra

被引：490

作者：

Furukawa, Hiroyasu ^{[1
]}

Kim, Jaheon ^{[2
]}

Ockwig, Nathan W. ^{[3
]}

O'Keeffe, Michael ^{[4
]}

Yaghi, Omar M. ^{[1
]}

机构：

[1] Univ Calif Los Angeles, Ctr Reticular Chem, Dept Chem & Biochem, Calif Nanosyst Inst, Los Angeles, CA 90095 USA

[2] Soongsil Univ, Dept Chem, Seoul 156743, South Korea

[3] Sandia Natl Labs, Dept Geochem, Albuquerque, NM 87185 USA

[4] Arizona State Univ, Dept Chem & Biochem, Tempe, AZ 85287 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2008年 / 130卷 / 35期

关键词：

D O I：

10.1021/ja803783c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Metal-organic polyhedra and frameworks (MOPS and MOFs) were prepared by linking square units M-2(CO2)(4) (M = Cu and Zn) with a variety of organic linkers designed to control the dimensionality (periodicity) and topology of the resulting structures. We describe the preparation, characterization, and crystal structures of 5 new MOPS and 11 new MOFs (termed MOP-14, -15, -17, -23, -24 and MOF-114, -115, -116, -117, -118, -119, -222, -601, -602, -603, -604) and show how their structures are related to the shape and functionality of the building blocks. The gas uptake behaviors of MOP-23 and MOF-601 to -603 are also presented as evidence that these structures have permanent porosity and rigid architectures.

引用

页码：11650 / 11661

页数：12

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