共 97 条
Homogeneous nucleation
被引:77
作者:
Gunton, JD
[1
]
机构:
[1] Lehigh Univ, Dept Phys, Bethlehem, PA 18015 USA
关键词:
homogeneous nucleation;
density functional theory;
numerical simulation;
D O I:
10.1023/A:1004598332758
中图分类号:
O4 [物理学];
学科分类号:
0702 ;
摘要:
Significant progress has been made in recent years in measuring homogeneous nucleation rates in a variety of liquid-vapor and liquid-solid transitions. These studies have revealed serious shortcomings of classical nucleation theory. New theoretical work and simulation studies of simplified model systems have provided a better understanding of homogeneous nucleation, but many challenges remain. This article summarizes some recent developments, with an emphasis on the field-theoretic approach pioneered by Cahn and Hilliard in their study of nucleation in a two-component incompressible fluid in 1959.
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页码:903 / 923
页数:21
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