A nonmechanical, membrane-based liquid pressurization system

被引:11
作者
Evans, CE
Noble, RD
Koval, CA
机构
[1] Univ Colorado, Dept Chem & Biochem, Boulder, CO 80309 USA
[2] Univ Colorado, Dept Chem & Biol Engn, Boulder, CO 80309 USA
关键词
D O I
10.1021/ie0504708
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
Nonmechanical pumping of liquids is of key importance for applications ranging from biomedical lab-on-a-chip systems to morphing mechanical structures. In this paper, we report a new, reversible micropumping and pressurization system, with no moving parts, that uses only modest external power. This new "e-pump" operates via a type of electro-osmosis (EO) in which a charge imbalance is created electrochemically across a cation-selective membrane, cations migrate to balance the charge, and solvent is transported across the membrane, along with the mobile cation. No gas is produced in this electrokinetic pumping system, so only liquids are involved in pumping and pressurization. In this proof-of-concept study, an aprotic solvent (dimethylformamide) was chosen to select the specific cation that is migrating (tetrapropylammonium ion). To date, pressures up to 23 atm have been successfully demonstrated.
引用
收藏
页码:472 / 475
页数:4
相关论文
共 19 条
[1]  
Adamson A.W., 1967, Physical chemistry of surfaces
[2]   Generating high-pressure sub-microliter flow rate in packed microchannel by electroosmotic force: potential application in microfluidic systems [J].
Chen, LX ;
Ma, JP ;
Tan, F ;
Guan, YF .
SENSORS AND ACTUATORS B-CHEMICAL, 2003, 88 (03) :260-265
[3]   Review of state of art of smart structures and integrated systems [J].
Chopra, I .
AIAA JOURNAL, 2002, 40 (11) :2145-2187
[4]  
HELFFERICH F, 1962, ION EXCHANGE, pCH8
[5]  
Izutsu K, 2002, ELECTROCHEMISTRY NON
[6]   PRESSURE-DRIVEN FLOW EXPERIMENTS IN MOLECULARLY NARROW, STRAIGHT PORES OF MOLECULAR DIMENSION IN MICA [J].
KNUDSTRUP, TG ;
BITSANIS, IA ;
WESTERMANNCLARK, GB .
LANGMUIR, 1995, 11 (03) :893-897
[7]   A review of micropumps [J].
Laser, DJ ;
Santiago, JG .
JOURNAL OF MICROMECHANICS AND MICROENGINEERING, 2004, 14 (06) :R35-R64
[8]  
LOEWY RG, 1997, SMART MATER STRUCT, V6, P11
[9]   State of understanding of Nafion [J].
Mauritz, KA ;
Moore, RB .
CHEMICAL REVIEWS, 2004, 104 (10) :4535-4585
[10]   On the efficiency of electrokinetic pumping of liquids through nanoscale channels [J].
Min, JY ;
Hasselbrink, EF ;
Kim, SJ .
SENSORS AND ACTUATORS B-CHEMICAL, 2004, 98 (2-3) :368-377