A new selective fluorescence chemosensor for Cu(II) in water

被引:60
作者
Beltramello, M
Gatos, M
Mancin, F
Tecilla, P
Tonellato, U
机构
[1] Univ Padua, Dipartimento Chim Organ, I-35131 Padua, Italy
[2] Univ Padua, CNR, Ctr Meccanismi Reaz Organ, I-35131 Padua, Italy
[3] Univ Trieste, Dipartimento Sci Chim, I-34127 Trieste, Italy
关键词
D O I
10.1016/S0040-4039(01)01965-7
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A new chemosensor for the Cu(II) ion has been realized by connecting via an amido bond an anthracenyl residue to the all cis 2,4.6-triamino-1,3,5-trihydroxycyclohexane ligand (TACI). This sensor is able to detect micromolar concentrations of Cu(II) ions in water at pH 7 without interference with many other divalent transition metal ions. (C) 2001 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:9143 / 9146
页数:4
相关论文
共 30 条
[1]   Synthesis of a novel thiazole based dipeptide chemosensor for Cu(II) in water [J].
Bhattacharya, S ;
Thomas, M .
TETRAHEDRON LETTERS, 2000, 41 (52) :10313-10317
[2]   Synthesis and solution structure analysis of a bispyrenyl bishydroxamate calix[4]arene-based receptor, a fluorescent chemosensor for Cu2+and Ni2+ metal ions [J].
Bodenant, B ;
Weil, T ;
Businelli-Pourcel, M ;
Fages, F ;
Barbe, B ;
Pianet, I ;
Laguerre, M .
JOURNAL OF ORGANIC CHEMISTRY, 1999, 64 (19) :7034-7039
[3]  
Cleij MC, 1996, GAZZ CHIM ITAL, V126, P827
[4]   Fluorescent chemosensor for organic guests and copper(II) ion based on dansyldiethylenetriamine-modified beta-cyclodextrin [J].
Corradini, R ;
Dossena, A ;
Galaverna, G ;
Marchelli, R ;
Panagia, A ;
Sartor, G .
JOURNAL OF ORGANIC CHEMISTRY, 1997, 62 (18) :6283-6289
[5]  
Czarnik A.W., 1993, ACS S SERIES
[6]   STEREOSELECTIVE FORMATION OF TERNARY COPPER(II) COMPLEXES OF (S)-AMINO-ACID AMIDES AND (R)-AMINO OR (S)-AMINO ACIDS IN AQUEOUS-SOLUTION [J].
DALLAVALLE, F ;
FOLESANI, G ;
MARCHELLI, R ;
GALAVERNA, G .
HELVETICA CHIMICA ACTA, 1994, 77 (06) :1623-1630
[7]   COPPER(II) COMPLEXES OF POTENTIALLY TERDENTATE N-2-[(R)-2-HYDROXYPROPYL]-(S)-PHENYLALANINAMIDE AND N-2-[(S)-2-HYDROXYPROPYL]-(S)-PHENYLALANINAMIDE FOR CHIRAL RECOGNITION - SYNTHESIS OF THE LIGANDS AND FORMATION-CONSTANTS [J].
DALLAVALLE, F ;
FOLESANI, G ;
BERTUZZI, T ;
CORRADINI, R ;
MARCHELLI, R .
HELVETICA CHIMICA ACTA, 1995, 78 (07) :1785-1792
[8]   Signaling recognition events with fluorescent sensors and switches [J].
de Silva, AP ;
Gunaratne, HQN ;
Gunnlaugsson, T ;
Huxley, AJM ;
McCoy, CP ;
Rademacher, JT ;
Rice, TE .
CHEMICAL REVIEWS, 1997, 97 (05) :1515-1566
[9]   A fluorescent chemosensor for the copper(II) ion [J].
DeSantis, G ;
Fabbrizzi, L ;
Licchelli, M ;
Mangano, C ;
Sacchi, D ;
Sardone, N .
INORGANICA CHIMICA ACTA, 1997, 257 (01) :69-76
[10]   Fluorescent sensors for transition metals based on electron-transfer and energy-transfer mechanisms [J].
Fabbrizzi, L ;
Licchelli, M ;
Pallavicini, P ;
Perotti, A ;
Taglietti, A ;
Sacchi, D .
CHEMISTRY-A EUROPEAN JOURNAL, 1996, 2 (01) :75-82