Synthesis and characterisation of a novel ruthenium organometallic cis-[Ru(bpy)(2)(npp)(Cl)]center dot BF4 where bpy=2,2'-bipyridyl and npp=4-(N-pyrrolyl)pyridine

被引：5

作者：

Atkins, MJ ^{[1
]}

Harwood, DJ ^{[1
]}

Lowry, RB ^{[1
]}

机构：

[1] UNIV PLYMOUTH,DEPT ENVIRONM SCI,PLYMOUTH PL4 8AA,DEVON,ENGLAND

来源：

INORGANICA CHIMICA ACTA | 1996年 / 244卷 / 02期

关键词：

ruthenium organometallic; NMR analysis;

D O I：

10.1016/0020-1693(96)05032-3

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The ruthenium(II) complex cis-[Ru(bpy)(2)(npp) (Cl)](+) where bpy=2,2'-bipyridyl and npp=4-(N-pyrrolyl) pyridine has been isolated from the reaction between cis-dichlorbis(bipyridine)ruthenium and 4-(N-pyrrolyl) pyridine and precipitated as the tetrafluoroborate salt. 270 MHz H-1 and C-13 NMR studies have been used to characterise this novel ruthenium complex together with IR and Raman data. The 270 MHz H-1 NMR spectra of 4-(N-pyrrolyl)pyridine and cis-[Ru(bpy)(2)(Cl)(2)] have also been recorded.

引用

页码：277 / 280

页数：4

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