Water-insoluble polymers containing amine, sulfonic acid, and carboxylic acid groups: Synthesis, characterization, and metal-ion-retention properties

被引：20

作者：

Rivas, BL ^{[1
]}

Villegas, S ^{[1
]}

Ruf, B ^{[1
]}

机构：

[1] Univ Concepcion, Fac Chem, Polymer Dept, Concepcion, Chile

来源：

JOURNAL OF APPLIED POLYMER SCIENCE | 2006年 / 99卷 / 06期

关键词：

radical copolymerization; resins; metal-polymer complexes;

D O I：

10.1002/app.22781

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Crosslinked poly(acryloylmorpholine) and its copolymers poly(acryloyl morpholine-co-acrylic acid) and poly(acryloylmorpholine-co-2-acrylamide-2-methyl-propane sulfonic acid) were synthesized by radical polymerization. The resins were completely insoluble in water and were characterized with Fourier transform infrared spectroscopy and thermal analysis. The metal ions Ag(I), Cu(II), Cd(II), Hg(II), Zn(II), Pb(II), Al(III), and Cr(III) were investigated under competitive and noncompetitive conditions by a batch equilibrium procedure. The resin-metal-ion equilibrium was achieved before 5 min. The recovery of the resin was investigated at 20 degrees C with different concentrations of HNO3 and HClO4 (c) 2006 Wiley Periodicals, Inc.

引用

页码：3266 / 3274

页数：9

共 24 条

[1]

[Anonymous], POLYM MAT ENCY

[2] Crown ethers: The search for selective ion ligating agents [J].

Bradshaw, JS ;

Izatt, RM .

ACCOUNTS OF CHEMICAL RESEARCH, 1997, 30 (08) :338-345

[3] Synthesis and properties of a copper selective chelating resin containing a salicylaldoxime group [J].

Ebraheem, KAK ;

Hamdi, ST .

REACTIVE & FUNCTIONAL POLYMERS, 1997, 34 (01) :5-10

[4] STUDIES OF SELECTIVE ADSORPTION RESINS .22. REMOVAL AND RECOVERY OF ARSENIC ION IN GEOTHERMAL POWER WASTE SOLUTION WITH CHELATING RESIN CONTAINING MERCAPTO GROUPS [J].

EGAWA, H ;

NONAKA, T ;

MAEDA, H .

SEPARATION SCIENCE AND TECHNOLOGY, 1985, 20 (9-10) :653-664

[5] THERMODYNAMIC AND KINETIC DATA FOR MACROCYCLE INTERACTION WITH CATIONS, ANIONS, AND NEUTRAL MOLECULES [J].

IZATT, RM ;

PAWLAK, K ;

BRADSHAW, JS ;

BRUENING, RL .

CHEMICAL REVIEWS, 1995, 95 (07) :2529-2586

[6] Co-ordination polymers [J].

Kaliyappan, T ;

Kannan, P .

PROGRESS IN POLYMER SCIENCE, 2000, 25 (03) :343-370

[7] Synthesis and complexing properties of resins containing aminocarboxylic acid as functional groups from diethylenetriaminepentaacetic acid bisanhydride and polyvinyl alcohols [J].

Montembault, V ;

Soutif, JC ;

Brosse, JC ;

Grote, M .

REACTIVE & FUNCTIONAL POLYMERS, 1999, 39 (03) :253-261

[8]

Moreno-Villoslada I, 2004, J CHIL CHEM SOC, V49, P121, DOI 10.4067/S0717-97072004000200003

[9]

Rivas BL, 2000, BOL SOC CHIL QUIM, V45, P165

[10] Sorption behavior of environmentally relevant metal cations of 4-vinylpyridine based resins [J].

Rivas, BL ;

Peric, IM ;

Maturana, HA ;

Fuentes, L .

POLYMER BULLETIN, 1999, 42 (03) :337-343

← 1 2 3 →