Spontaneous stabilization and isolation of dispersible bimetallic coordination nanoparticles of CsxNi[Cr(CN)6]y

被引:76
作者
Brinzei, Daniela
Catala, Laure [1 ]
Louvain, Nicolas
Rogez, Guillaume
Stephan, Odile
Gloter, Alexandre
Mallah, Talal
机构
[1] Univ Paris 11, CNRS, UMR 8182, ICMMO Equipe Chim Inorgan, F-91405 Orsay, France
[2] ULP, CNRS, UMR 7504, Inst Phys & Chim Mat Strasbourg, F-67034 Strasbourg 2, France
[3] Univ Paris 11, CNRS, UMR 8502, Phys Solides Lab, F-91405 Orsay, France
关键词
D O I
10.1039/b605221e
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The spontaneous stabilization of 6.5 nm bimetallic Ni - Cr cyanide bridged nanoparticles was achieved in water. Dispersible particles were recovered from solution using two different coating agents. The magnetic studies of the particles in the powder form show either a superparamagnetic or a spin glass like behaviour depending on the isolation technique used.
引用
收藏
页码:2593 / 2599
页数:7
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