Fluoropolymer indium-tin-oxide buffer layers for improved power conversion in organic photovoltaics

被引:46
作者
Kang, Bonan [1 ,2 ]
Tan, L. W. [1 ]
Silva, S. R. P. [1 ]
机构
[1] Univ Surrey, Adv Technol Inst, Nanoelect Ctr, Surrey GU2 7XH, England
[2] Jilin Univ Reg, State Key Lab Integrated Optoelect, Changchun 130012, Peoples R China
基金
英国工程与自然科学研究理事会;
关键词
D O I
10.1063/1.2983742
中图分类号
O59 [应用物理学];
学科分类号
摘要
We investigate the effects of polytetrafluoroethylene (PTFE) on poly (3-hexylthiophene): phenyl-C61- butyric acid methyl ester (P3HT:PCBM) based organic photovoltaic (OPV) devices by inserting thermally evaporated PTFE films between indium-tin-oxide (ITO) and P3HT: PCBM layers. Significant improvement in terms of open-circuit voltage, short-circuit current, and thereby in its commensurate power conversion efficiency is achieved compared to devices with poly (3,4-ethylenedioxythiophene): poly (styrene-sulfonate) layers. The OPVs performance enhancement is attributed to the formation of an artificial dipole layer resulting from the rich, negatively charged fluorine that facilitates the hole extraction process. This result shows the high potential of PTFE as a low cost and stable ITO buffer layer for OPV devices. (C) 2008 American Institute of Physics.
引用
收藏
页数:3
相关论文
共 18 条
[1]   ORIENTATIONAL PROBING OF POLYMERIC THIN-FILMS BY NEXAFS - CALCULATIONS ON POLYTETRAFLUOROETHYLENE [J].
AGREN, H ;
CARRAVETTA, V ;
VAHTRAS, O ;
PETTERSSON, LGM .
PHYSICAL REVIEW B, 1995, 51 (24) :17848-17855
[2]   Bright single-active layer small-molecular organic light-emitting diodes with a polytetrafluoroethylene barrier [J].
Gao, YD ;
Wang, LD ;
Zhang, DQ ;
Duan, L ;
Dong, GF ;
Qiu, Y .
APPLIED PHYSICS LETTERS, 2003, 82 (02) :155-157
[3]   Optical, conductive and magnetic properties of electrochemically prepared alkylated poly(3,4-ethylenedioxythiophene)s [J].
Groenendaal, L ;
Zotti, G ;
Jonas, F .
SYNTHETIC METALS, 2001, 118 (1-3) :105-109
[4]   IN-SITU SPECTROSCOPIC INVESTIGATIONS OF ELECTROCHROMISM AND ION-TRANSPORT IN A POLY(3,4-ETHYLENEDIOXYTHIOPHENE) ELECTRODE IN A SOLID-STATE ELECTROCHEMICAL-CELL [J].
GUSTAFSSON, JC ;
LIEDBERG, B ;
INGANAS, O .
SOLID STATE IONICS, 1994, 69 (02) :145-152
[5]   High-efficiency hole extraction/electron-blocking layer to replace poly(3,4-ethylenedioxythiophene):poly(styrene sulfonate) in bulk-heterojunction polymer solar cells [J].
Hains, Alexander W. ;
Marks, Tobin J. .
APPLIED PHYSICS LETTERS, 2008, 92 (02)
[6]   Pulsed plasma polymerization of an aromatic perfluorocarbon monomer: Formation of low dielectric constant, high thermal stability films [J].
Han, LCM ;
Timmons, RB ;
Lee, WW .
JOURNAL OF VACUUM SCIENCE & TECHNOLOGY B, 2000, 18 (02) :799-804
[7]  
Heuer HW, 2002, ADV FUNCT MATER, V12, P89, DOI 10.1002/1616-3028(20020201)12:2<89::AID-ADFM89>3.0.CO
[8]  
2-1
[9]   Hybrid nanorod-polymer solar cells [J].
Huynh, WU ;
Dittmer, JJ ;
Alivisatos, AP .
SCIENCE, 2002, 295 (5564) :2425-2427
[10]   Three-dimensional inhomogeneities in PEDOT:PSS films [J].
Kemerink, M ;
Timpanaro, S ;
de Kok, MM ;
Meulenkamp, EA ;
Touwslager, FJ .
JOURNAL OF PHYSICAL CHEMISTRY B, 2004, 108 (49) :18820-18825