Model electrodes with defined mesoscopic structure

被引：21

作者：

Friedrich, KA ^{[1
]}

Marmann, A ^{[1
]}

Stimming, U ^{[1
]}

Unkauf, W ^{[1
]}

Vogel, R ^{[1
]}

机构：

[1] FORSCHUNGSZENTRUM JULICH, FORSCHUNGSZENTRUM, INST ENERGIEVERFAHRENSTECH, D-52425 JULICH, GERMANY

来源：

FRESENIUS JOURNAL OF ANALYTICAL CHEMISTRY | 1997年 / 358卷 / 1-2期

关键词：

D O I：

10.1007/s002160050372

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

Model electrodes with defined mesoscopic structure were either generated by adsorption of surfactant stabilized metal clusters from colloidal solution on a support of gold or by electrochemical deposition of platinum on gold substrates. Both types of model electrodes were characterized by STM (scanning tunnelling microscopy), cyclic voltammetry and electrooxidation of adsorbed CO. The supported colloidal Pt as well as the electrochemically deposited Pt revealed different reactivities regarding the CO monolayer electrooxidation as compared to a polycrystalline Pt bulk electrode. Tn addition, in-situ FTIR (Fourier transformed infrared) spectroscopy was applied to characterize CO adsorbed on electrochemically deposited Pt on gold. Combined with the structural information from STM it seems likely that the differences regarding the catalytic properties of the model electrodes are due to different coverages of the substrate with catalyst particles.

引用

页码：163 / 165

页数：3

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