The bonding and structure of B-N sandwich complexes

被引：19

作者：

Bridgeman, AJ ^{[1
]}

Rothery, J ^{[1
]}

机构：

[1] Univ Cambridge, Chem Labs, Cambridge CB2 1EW, England

来源：

INORGANICA CHIMICA ACTA | 1999年 / 288卷 / 01期

关键词：

boron-nitrogen complexes; sandwich complexes; metal complexes;

D O I：

10.1016/S0020-1693(99)00007-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The structures and bonding of pi-complexes formed by the completely inorganic ring systems B2N2R4 and B2N3R4- have been investigated using density functional calculations. These rings are isoelectronic with cyclobutadiene and the cyclopentadienyl anion, respectively and a detailed comparison of their bonding characteristics is described. The optimized structure of (eta(5)-B2N3H4)(2)Fe, a fully inorganic ferrocene analogue, is reported. (C) 1999 Elsevier Science S.A. All rights reserved.

引用

页码：17 / 28

页数：12

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