Living diradical polymerization

被引：61

作者：

Hammouch, SO ^{[1
]}

Catala, JM ^{[1
]}

机构：

[1] INST CHARLES SADRON,CNRS,ULP,F-67083 STRASBOURG,FRANCE

来源：

MACROMOLECULAR RAPID COMMUNICATIONS | 1996年 / 17卷 / 02期

关键词：

D O I：

10.1002/marc.1996.030170212

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

A diradical initiator containing two thermoreversible bonds was prepared and used for the polymerization of styrene at 90 degrees C. The monomer consumption and the variation of the molecular weight were monitored with time. The results show that the process can be considered as living and that the polymerization rate is independent of the radical initiator concentration. By elemental analysis of the chain ends it was concluded that the propagation reaction occurs at both ends.

引用

页码：149 / 154

页数：6

共 15 条

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