In situ synthesis of nano silver on polyester using NaOH/Nano TiO2

被引:80
作者
Allahyarzadeh, Vida [1 ]
Montazer, Majid [1 ]
Nejad, Nahid Hemmati [1 ]
Samadi, Nasrin [2 ,3 ]
机构
[1] Amirkabir Univ Technol, Ctr Excellence Text, Text Engn Dept, Tehran, Iran
[2] Univ Tehran Med Sci, Fac Pharm, Dept Drug & Food Control, Tehran, Iran
[3] Univ Tehran Med Sci, Pharmaceut Qual Assurance Res Ctr, Tehran, Iran
关键词
polyester; alkali hydrolysis; nano silver; nano TiO2; antibacterial; self-cleaning; GREEN SYNTHESIS; ALKALINE-HYDROLYSIS; ETHYLENE-GLYCOL; POLYOL PROCESS; NANOPARTICLES; POLY(ETHYLENE-TEREPHTHALATE); FABRICS; SODIUM; GROWTH; NANOSTRUCTURES;
D O I
10.1002/app.38907
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Alkali hydrolysis of polyester along with application of nano silver/nano TiO2 to produce hydrolyzed polyester fabric with antibacterial and self-cleaning properties is a very interesting subject. In this article, a novel idea is introduced to achieve a polyester fabric with self-cleaning and antibacterial properties with a good feeling handle in one step. The polyester fabric is hydrolyzed in alkali media to enhance the surface activity, improve nanoparticle absorption, and produce ethylene glycol for reducing silver nitrate into nano silver. XRD pattern confirms the presence of nanoparticles with crystal size of 10 nm on the fabric surface and FESEM pictures show the distribution of nanocomposite particles on the fiber surfaces with average size of 54 nm. The degradation of Methylene Blue under daylight irradiation confirms the photoactivity of nano TiO2 on the polyester fabric. Also, very good bactericidal efficiency is obtained against S. aureus and E. coli. Interestingly, the fabric tensile strength improves even with the action of alkali in surface hydrolysis of polyester. (c) 2013 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 129: 892-900, 2013
引用
收藏
页码:892 / 900
页数:9
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