Application of gas chromatography/mass spectrometry in studies on separation and identification of organic species in coals

被引:75
作者
Fan, Xing [1 ]
Wei, Xian-Yong [1 ]
Zong, Zhi-Min [1 ]
机构
[1] China Univ Min & Technol, Minist Educ, Key Lab Coal Proc & Efficient Utilizat, Xuzhou 221116, Jiangsu, Peoples R China
基金
中国国家自然科学基金; 中国博士后科学基金;
关键词
GC/MS; Extraction; Liquefaction; Oxidation; Organic species; METHANOL-MEDIATED EXTRACTION; HYDROGEN-TRANSFER; PHENOLIC-COMPOUNDS; MASS-SPECTROMETRY; UPPER FREEPORT; SHENFU COAL; OXIDATION; IONIZATION; RESIDUES; FRACTION;
D O I
10.1016/j.fuel.2012.09.003
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
080707 [能源环境工程]; 082001 [油气井工程];
摘要
The use of gas chromatography/mass spectrometry (GC/MS) in the investigation of coal structures and identification for composition of small molecules (with molecular weight at or less than 500 Da) was reviewed. Macromolecules and small molecules coexist in coals. Understanding the role of small molecules is the fundamental for effective, clean and value-added utilization of coals. For coals after treatments (extraction, oxidation and liquefaction), small molecules can be extracted from the macromolecular network and analyzed using GC/MS. Variou skinds of organic species were identified using GC/MS, which gave explanation for coal structures and mechanisms for coal liquefaction and oxidation. (C) 2012 Elsevier Ltd. All rights reserved.
引用
收藏
页码:28 / 32
页数:5
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