Organolanthanides as single component homogeneous catalysts for isoprene-hex-1-ene co-polymerisation

被引：15

作者：

Barbier-Baudry, D ^{[1
]}

Dormond, A ^{[1
]}

Desmurs, P ^{[1
]}

机构：

[1] Univ Bourgogne, Fac Sci Gabriel, Lab Synth & Electrosynth Organomet, UMR 5632, F-21000 Dijon, France

来源：

COMPTES RENDUS DE L ACADEMIE DES SCIENCES SERIE II FASCICULE C-CHIMIE | 1999年 / 2卷 / 7-8期

关键词：

lanthanide; isoprene; hex-1-ene; co-polymerisation;

D O I：

10.1016/S1387-1609(00)88548-5

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Bisallylansalanthanide complexes act as single component catalysts of diene polymerisation; from an equimolar mixture of isoprene and hex-1-ene, a co-polymer hex-1-ene/isoprene = 1:10 is obtained, this copolymer is essentially formed of 1,4-transpolyisoprene blocks separated by only one inserted hexyl group. (C) 1999 Academie des sciences/Editions scientifiques et medicales Elsevier SAS.

引用

页码：375 / 378

页数：4

共 27 条

[1]

Baudry-Barbier D, 1998, EUR J INORG CHEM, P1721

[2] THE SYNTHESIS AND NUCLEAR-MAGNETIC-RESONANCE INVESTIGATION OF THE STRUCTURE AND CHEMICAL-DYNAMICS OF NEW ANIONIC TETRA-ALLYL COMPLEXES OF LANTHANIDE IONS [J].