Intensities and rates in the spectral domain without eigenvectors

被引:23
作者
Gruebele, M [1 ]
机构
[1] UNIV ILLINOIS,BECKMAN INST ADV SCI & TECHNOL,URBANA,IL 61801
关键词
D O I
10.1063/1.470940
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
An exact quantum-mechanical formula is presented which relates energy level fluctuations of a complex multidimensional quantum system to its spectrum. The formalism presented here can be used to efficiently calculate the spectrum and linewidth (rate), without recourse to eigenvectors of the Hamiltonian matrix, and yields insights into the relation between level fluctuations and spectral features. (C) 1996 American Institute of Physics.
引用
收藏
页码:2453 / 2456
页数:4
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