Electrochemically induced alumina coatings on stainless steel: Composition and behaviour at high temperature

被引:19
作者
Aries, L [1 ]
Roy, J [1 ]
Sotoul, J [1 ]
Pontet, V [1 ]
Costeseque, P [1 ]
Aigouy, T [1 ]
机构
[1] UNIV TOULOUSE 3,URA CNRS 67,CRMTG,LAB MINERAL & CRISTALLOG,F-31000 TOULOUSE,FRANCE
关键词
D O I
10.1007/BF00253460
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Alumina coatings were formed by electrolytic treatment on an Fe-17% Cr stainless steel functionalized by surface conversion treatment to induce a particular surface morphology, suited to anchoring the ceramic layer. As deposited, the coatings appeared amorphous. They were composed of two layers: the superficial layer was constituted only of aluminium compounds while the deep layer had a composition gradient. Heating the coated steel caused interface reactions between the electrochemically-induced deposit and the initial conversion coating compounds. These reactions act to strengthen coat adhesion to the substrate with formation of crystallized mixed oxide such as Fe(Cr,Al)(2)O-4. Moreover, Al2O3 phases appeared and acted as a barrier which prevented the thermal oxidation of the stainless steel.
引用
收藏
页码:617 / 622
页数:6
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