Proton conducting polymer gel electrolytes

被引：34

作者：

Zukowska, G ^{[1
]}

Rogowska, M ^{[1
]}

Weczkowska, E ^{[1
]}

Wieczorek, W ^{[1
]}

机构：

[1] Warsaw Univ Technol, Fac Chem, PL-00664 Warsaw, Poland

来源：

SOLID STATE IONICS | 1999年 / 119卷 / 1-4期

关键词：

gel electrolytes; proton conduction; poly(vinylidene fluoride); phosphoric acid;

D O I：

10.1016/S0167-2738(98)00516-5

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Novel proton conducting gel electrolytes from poly(vinylidene fluoride)-dimethylformamide-H3PO4 system are synthesized and characterized by impedance spectroscopy, infra-red spectroscopy and differential scanning calorimetry. Highly conducting (5 x 10(-4) S/cm at 20 degrees C) colorless polymeric membranes are obtained in a relatively narrow component concentration range. The gel electrolytes studied are thermally stable up to 70-120 degrees C as shown by the DSC experiments. (C) 1999 Elsevier Science B.V. All rights reserved.

引用

页码：289 / 293

页数：5