Coordination polymers composed of copper(II), trimesic acid, and imidazole: 3D architecture stabilized by hydrogen bonding

被引：120

作者：

Cheng, DP ^{[1
]}

Khan, MA ^{[1
]}

Houser, RP ^{[1
]}

机构：

[1] Univ Oklahoma, Dept Chem & Biochem, Norman, OK 73019 USA

来源：

INORGANIC CHEMISTRY | 2001年 / 40卷 / 27期

关键词：

D O I：

10.1021/ic015609v

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The coordination polymers {[CU3(TMA)(2)(Im)(6)(H2O)]* 7H(2)O}n (1) and {[CU3(TMA)(2)(Me-IM)(6)(H2O)]*16H(2)O}(n) (2) were synthesized by combining copper sulfate, TMA, and either Im or Me-Im in water. Single-crystal X-ray diffraction studies revealed that both compounds are composed of 2D sheets of Cu2+ cations and TMA(3-) anions. Hydrogen bonding between sheets in 1 stabilizes its 3D structure, while 2 is destabilized because of the absence of intersheet hydrogen bonding.

引用

页码：6858 / +

页数：3

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