A novel electric ion resonance cell design with high signal-to-noise ratio and low distortion for Fourier transform mass spectrometry

Performing wideband ion image current detection mass spectrometry experiments with an electric ion trap-e.g., the Paul trap-is a difficult task, as there is a strong crosstalk current induced by the high voltages of the radio frequency (rf) storage field. In a classic Paul trap the metallic hyperbolic electrodes (a ring electrode and two end cap electrodes) are shaped following the isopotential lines of the quadrupole potential distribution. In our new design the ring electrode is replaced by a cylindrical series of ring electrodes with a parabolic potential distribution, whereas the end cap electrodes are used without modification. Thus the quadrupole field within the trap remains unchanged but the capacitances between the electrodes and therefore the crosstalk currents are significantly reduced. The remaining crosstalk is balanced out by an electronic compensation technique. As a consequence the weak signals of the ion-induced charge can be detected with a wideband low-noise amplifier to perform Fourier transform mass spectrometry experiments with improved signal-to-noise ratio. (J Am Soc Mass Spectrom 1999, 10, 1000-1007) (C) 1999 American Society for Mass Spectrometry.