Metal-radical approach to high spin molecules:: a pentanuclear μ-cyano Cr(III)Ni(II)(radical)2 complex with a low-lying S=9 ground state

被引:71
作者
Marvilliers, A
Pei, Y
Boquera, JC
Vostrikova, KE
Paulsen, C
Rivière, E
Audière, JP
Mallah, T [1 ]
机构
[1] Univ Paris Sud, Chim Inorgan Lab, CNRS, UMR 8613, F-91405 Orsay, France
[2] Russian Acad Sci, Inst Inorgan Chem, Novosibirsk 630090, Russia
[3] CNRS, Ctr Rech Tres Basses Temp, F-38054 Grenoble, France
关键词
D O I
10.1039/a905736f
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Reacting hexacyanochromate(III) with a mononuclear Ni(II) complex chelated by two bidentate organic radicals leads to a pentanuclear complex with three different kinds of paramagnetic species interacting ferromagnetically and stabilising a high spin S = 9 ground state.
引用
收藏
页码:1951 / 1952
页数:2
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