Glasgow lake: An early-warning sentinel of lake acidification in cape breton highlands national park (Nova scotia, canada)

In contrast to other lakes studied in Cape Breton Highlands National Park (Nova Scotia, Canada), our paleolimnological results indicated that Glasgow Lake has been impacted by acidic deposition starting in the early 1900s. Based on analysis of diatom assemblages, the lake experienced a decrease in diatom-inferred lakewater pH from a pre-industrial pH of similar to 5.8 to a current pH of 5.3 (2000-2002 measured mean pH = 5.0) as well as a decrease in diatom-inferred Gran-alkalinity. In this study, diatom-based paleolimnological techniques were used in conjunction with a dynamic biogeochemical model (MAGIC) to assess both the timing and extent of the acidification trend, as well as determine a probable explanation as to why this lake, and none of the other 15 Cape Breton Highlands lakes studied for paleolimnology thus far, acidified under a peak non-marine sulphate deposition load of 43.6 mmol(c) m-2supercript stop year(-1) in the mid-1970s. Steady-state models estimate that Glasgow Lake had the lowest buffering capacity of six study lakes and estimated critical sulphate loading of < 1 mmol(c) m(-2) year(-1). MAGIC also estimated a loss of charge balance alkalinity from a pre-1850 value of 38 mu mol(c) l(-1) to a low of 12 mu mol(c) l(-1). While no evidence of biological recovery has been recorded, MAGIC estimates an increase in charge balance alkalinity to 27 mu mol(c) l(-1) in 2002 in response to decreased SO2 emissions. Of the five other lakes that were modelled, all showed trends towards more acidic states and subsequent increases in charge balance alkalinity; however, the empirical paleo-diatom approach applied to these lakes showed no evidence of acidification. Thus, Glasgow Lake has the lowest buffering capacity among the Cape Breton Highland study lakes and serves as a sentinel of potential acidification trends and recovery in this region.