First examples of the catalytic asymmetric ring-opening of meso 1,2-dioxines utilising cobalt(II) complexes with optically active tetradentate Schiff base ligands: formation of enantio-enriched cyclopropanes

被引：55

作者：

Avery, TD ^{[1
]}

Jenkins, NF ^{[1
]}

Kimber, MC ^{[1
]}

Lupton, DW ^{[1
]}

Taylor, DK ^{[1
]}

机构：

[1] Univ Adelaide, Dept Chem, Adelaide, SA 5005, Australia

来源：

CHEMICAL COMMUNICATIONS | 2002年 / 01期

关键词：

D O I：

10.1039/b109187p

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The combination of chiral cobalt beta-ketoiminato or cobalt salen complexes and meso 1,2-dioxines leads to catalytic asymmetric ring-opening affording enantio-enriched cis gamma-hydroxy enones; subsequent capture by an ylide affords enantio-enriched cyclopropanes.

引用

页码：28 / 29

页数：2

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