Synthesis of a gable bis-porphyrin linked with a bicyclo[2.2.2]octadiene ring and its conversion into a conjugated planar bis-porphyrin

被引：32

作者：

Ito, S

Nakamoto, K

Uno, H

Murashima, T

Ono, N ^{[1
]}

机构：

[1] Ehime Univ, Fac Sci, Dept Chem, Matsuyama, Ehime 7908577, Japan

[2] Ehime Univ, Adv Instrumentat Ctr Chem Anal, Matsuyama, Ehime 7908577, Japan

来源：

CHEMICAL COMMUNICATIONS | 2001年 / 24期

关键词：

D O I：

10.1039/b108391k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A soluble porphyrin dimer linked with bicyclo[2.2.2]octadiene was converted in to insoluble conjugated porphyrin dimer by heating at 200 degreesC, this provides a new strategy for the process control of conjugated porphyrins.

引用

页码：2696 / 2697

页数：2

共 26 条

[1] Building molecular wires from the colours of life: conjugated porphyrin oligomers [J].

Anderson, HL .

CHEMICAL COMMUNICATIONS, 1999, (23) :2323-2330

[2] Triplet energy transfer in porphyrin dimers:: Comparison between π- and σ-chromophore bridged systems [J].

Andréasson, J ;

Kajanus, J ;

Mårtensson, J ;

Albinsson, B .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (40) :9844-9845

[3] A new strategy for construction of covalently linked giant porphyrin arrays with one, two, and three dimensionally arranged architectures [J].

Aratani, N ;

Osuka, A .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 2001, 74 (08) :1361-1379

[4]

Arnold DP, 2000, SYNLETT, P296

[5]

BONDIF A, 1994, J CHEM SOC CHEM COMM, P2096

[6]

Burrell AK, 1998, SYNLETT, P1297

[7] MOLECULAR CATALYSTS FOR MULTIELECTRON REDOX REACTIONS OF SMALL MOLECULES - THE COFACIAL METALLODIPORPHYRIN APPROACH [J].

COLLMAN, JP ;

WAGENKNECHT, PS ;

HUTCHISON, JE .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1994, 33 (15-16) :1537-1554

[8] SYNTHESIS OF PORPHYRIN-2,3,12,13-TETRAONES AND PORPHYRIN-2,3,7,8-TETRAONES - BUILDING-BLOCKS FOR THE SYNTHESIS OF EXTENDED PORPHYRIN ARRAYS [J].

CROSSLEY, MJ ;

GOVENLOCK, LJ ;

PRASHAR, JK .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1995, (23) :2379-2380

[9]

Graça M, 1999, CHEM COMMUN, P1771

[10] First observation of excited triplet dimers with strong intramolecular interactions:: planar binuclear phthalocyanines [J].

Ishii, K ;

Kobayashi, N ;

Higashi, K ;

Osa, T ;

Lelièvre, D ;

Simon, J ;

Yamauchi, S .

CHEMICAL COMMUNICATIONS, 1999, (11) :969-970

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